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Sulfur is an essential ingredient in Voltz. It provides an alternative way to obtain gunpowder compared to risking your life fighting creepers.To find it, you just need to find Lava as Sulphur is found there, usually within about 1 or 2 blocks. In order to make 5 gunpowder (1 TNT's equivalent) it requires 8 sulphur and 1 coal.
As TNT forms the basis of every explosive in Voltz, this is not to be underestimated.